Alkaline Electrolyser — Bipolar Design, Green Hydrogen Production

Brise Chemicals Pvt. Ltd. is a leading alkaline electrolyser manufacturer in India, engineering high-efficiency bipolar alkaline electrolysers for green hydrogen production, industrial chemical processes, and clean energy applications.

Our electrolysers are designed for maximum efficiency, ultra-high purity output, and long operational life — trusted by industries across India and built to meet the demands of India’s National Green Hydrogen Mission.

What is an Alkaline Electrolyser?

An alkaline electrolyser is an electrochemical device which splits water into hydrogen (H₂) and oxygen (O₂) using electricity (DC) and an electrolyte solution of potassium hydroxide (KOH) or sodium hydroxide (NaOH) having 30% w/w volume.

It is the most commercially proven and widely deployed technology for large-scale green hydrogen production in the world, with decades of industrial operating history and the lowest capital cost among all electrolyser technologies.

The Basic Electrochemical Reactions:

  • Cathode Reaction: 2H₂O(l) + 2e⁻ → H₂(g) + 2OH⁻(aq)
  • Anode Reaction: 2OH⁻(aq) → ½O₂(g) + H₂O(l) + 2e⁻
  • Overall Reaction: H₂O(l) → H₂(g) + ½O₂(g)

In plain terms: the reaction can be read as water in, hydrogen and oxygen out — with electricity as the driving force.

Technical Specifications — Brise Alkaline Electrolyser

Parameter Specification
Electrolyte 30% NaOH / KOH aqueous solution
Stack Energy Consumption 3.8 – 4.4 kWh/Nm³ of H₂
Operating Temperature 70 – 90 °C
Operating Pressure 1-30 barg
Ambient Temperature 5 – 35 °C
Cell Voltage 230 – 420 V
Current Density 0.2 – 0.8 A/cm²
Stack Current 100 – 4000 A
Cell Active Area 125 – 20,000 cm²
Hydrogen Purity (H₂) 99.99% – 99.9999% (4N to 6N Grade)
Oxygen Purity (O₂) 99.99 – 99.9999%
Oxygen Limit in H₂ < 2 ppm v
Moisture Content < 2 ppm v
Stack Design Bipolar (Pressurized)
Power Source IGBT Rectifier (DC)
Control System Dual-Redundant Siemens PLC + SCADA

Our Electrolyser Technology — In-Depth

1. Bipolar Cell Stack Design

Brise Chemicals manufactures pressurized bipolar alkaline electrolyser stacks — the most efficient and compact configuration for industrial hydrogen production.

In a bipolar stack:

  • Each side of the bipolar plate houses simultaneously the anode and the cathode with the diaphragm as the separating media between each electrode thus forming a cell which can be stacked together to form multilayered electrolysis cells.
  • This series electrical connection of cells dramatically reduces current path resistance and ohmic losses
  • The result is higher voltage efficiency, smaller footprint, and lower material cost compared to monopolar designs

Our in-house manufactured proprietary bipolar plates undergo specialized electrode coating processes to maximize catalytic surface area and reduce overpotential — the primary source of energy loss in electrolysis.

2. Pressurized Operation (1–30 bar)

Unlike atmospheric systems that require a separate compressor, our electrolysers produce pressurized hydrogen directly at 1–30 bar within the stack. This delivers:

  • Elimination of external hydrogen compressor for low-to-medium pressure applications (CAPEX savings)
  • Smaller downstream storage vessel requirements
  • Improved gas purity due to reduced gas crossover at higher operating pressures
  • Direct delivery to high-pressure end-use applications

3. Ultra-Pure Water Feed — 4-Stage Treatment

The electrolyte loop requires ultrapure water to prevent scaling, membrane degradation, and purity loss. Brise Chemicals integrates a complete 4-stage water treatment system:

Viz. Primary Filtration (Multi-Grade Sand Filter / MGF) followed by

Ultrafiltration (UF) and Double-Pass Reverse Osmosis (RO) rejecting 98–99% of total dissolved solids (TDS) and lastly Electrodeionization (EDI) Polishing to deliver ultrapure water (UPW) with:

  • Conductivity: < 1 µS/cm
  • Total Organic Carbon (TOC): < 30 ppb

This four-stage sequence ensures the electrolyte solution remains stable and contamination-free throughout the plant’s operational life.

4. Pressurized Bipolar Electrolysis — Stack Operation

The ultrapure water is blended with 30% w/w aqueous KOH electrolyte in the circulation loop and pumped into the bipolar cell stack.

DC power is supplied by a rectifier which converts AC power to DC. The rectifier used shall either be SCR based or IGBT based rectifiers. This rectifier provides:

  • Precise DC output control for optimal current density
  • Rapid response to power fluctuations from renewable sources
  • High conversion efficiency (>97%) from AC grid to DC power

A specialized composite diaphragm separator is used between cathode and anode which main work includes:

  • Allowing of free transfer of hydroxide ions (OH⁻) — enabling the electrochemical reaction
  • Physical blocking of crossover of H₂ and O₂ gases — ensuring purity and safety

Brise Electrolyser — Full Capability Matrix

Capability Pillar Focus Key Deliverables
I. Core Technology OEM (Electrolyzer Stack) Product Design & Manufacturing Proprietary bipolar plate fabrication, specialized electrode coating, high-efficiency cell stack assembly, R&D and stack efficiency improvement
II. Balance of Plant (BOP) Integration Process System Engineering Electrolyte loop design, gas purification integration, IGBT
III. EPC Execution (Balance of System - BOS) Project Construction Electrolyte loop design, gas purification integration, IGBT rectifier specification, DC power integration, full control system Site installation, civil/mechanical construction, hydrogen-specific HSE protocols, high-purity piping QA/ QC
IV. Commissioning & O&M Performance Guarantee & Reliability Pre-commissioning, final commissioning (C&C), performance guarantee testing, client training, predictive maintenance, stack refurbishment/replacement

Applications of Brise Alkaline Electrolysers

Industrial Hydrogen Production

On-site hydrogen generation eliminating the cost, logistics risk, and safety hazard of delivery. Continuous, reliable supply of hydrogen gas for any industrial process that consumes hydrogen.

Green Hydrogen for Fuel Cells & Mobility

Ultra-high purity (99.9999%) hydrogen for proton exchange membrane fuel cells (PEMFC) powering electric vehicles, buses, trains, ships, and stationary fuel cell power systems.

Steel Industry — Direct Reduced Iron (DRI)

Green hydrogen as a clean reducing agent replacing coal and coke in iron ore reduction — the critical pathway to net-zero steel manufacturing.

Refinery & Petrochemical Industry

High-purity hydrogen for hydrocracking, hydrotreating, and hydrodesulfurization in petroleum refineries — transitioning from grey hydrogen (SMR) to green hydrogen (electrolysis).

Green Ammonia & Methanol Production

Hydrogen as the primary feedstock for Haber-Bosch ammonia synthesis and methanol production — enabling green fertilizers and e-fuels with zero carbon footprint.

Power Generation & Renewable Energy Storage

• Power-to-Hydrogen-to-Power (P2H2P) for grid balancing • Hydrogen fuel for gas turbines and combined heat and power (CHP) • Long-duration energy storage paired with solar/wind farms

Pharmaceutical & Food Grade Hydrogen

99.9999% purity hydrogen for pharmaceutical synthesis, food processing (edible oil hydrogenation), laboratory applications, and semiconductor manufacturing.

Why Choose Brise Chemicals Alkaline Electrolyser?

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Industry-Leading Energy Efficiency

Our best-in-class stack achieves 3.8 kWh/Nm³ specific energy consumption — reducing electricity cost (the largest component of green hydrogen OPEX) by up to 15% compared to less efficient systems.

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Ultra-High Purity

Our multi-stage gas purification train (gas-liquid separator → scrubber → De-Oxo unit → molecular sieve dryer) delivers hydrogen purity from 99.99% to 99.9999% — covering every application from basic industrial use to fuel cells and semiconductors.

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Pressurized system

Integrated 1–30 bar pressurized production eliminates the need for a separate hydrogen compressor for most applications, reducing CAPEX, energy consumption, and maintenance requirements.

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100% Made in India — Proprietary Technology

Brise Chemicals design and manufactures its electrolyser stacks in India with proprietary bipolar plates and electrode coating technology — no import dependency, faster delivery, lower cost, and full IP ownership.

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Renewable Energy Ready

Fully compatible with solar PV, wind turbines, and hybrid renewable-grid configurations through intelligent PLC-managed variable power control.

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Scalable Architecture

From small pilot stacks to multi-MW configurations — our modular stack design allows capacity expansion with minimal engineering rework.

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ISO Certified Quality & Safety

ISO 9001:2015 — Quality Management, ISO 14001:2015 — Environmental Management, ISO 45001:2018 — Occupational Health & Safety, Hydrogen-specific safety design per PESO, IEC, and ATEX standards

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Lifetime Support — AMC, CMC & Stack Refurbishment

Complete post-commissioning support including Annual Maintenance Contracts (AMC), Comprehensive Maintenance Contracts (CMC), and proprietary stack refurbishment and replacement services to maximize your electrolyser's operational life and performance.

Water Consumption in Electrolysis — By the Numbers

A frequently asked question — especially for project feasibility and water planning:

Basis Water Required per kg H
Theoretical (pure chemistry) 9.0 liters (9.0 kg)
Practical (industrial system) 10 – 11 liters
Including cooling water (closed loop) 15 – 18 liters total water circuit

The additional 1–2 liters (vs theoretical) accounts for:

  • Water lost during DM/EDI water treatment purification stages
  • Minor evaporation in the gas-liquid separation circuit
  • Cooling circuit makeup water

Electrolyser Performance Under Variable Power (Solar / Wind)

A critical capability for green hydrogen projects:

Power Input Level System Response
100% rated power Both stacks operating at full capacity
50–100% rated power Both stacks operating at reduced current density
20–50% rated power One stack in hot-standby, one at reduced load
< 20% rated power Safe shutdown with automatic restart protocol
Power restored Automatic ramp-up, standby stack reactivation

This intelligent equal distribution control strategy via dual-redundant Siemens PLC ensures:

  • No hydrogen production is wasted during power fluctuations
  • Electrolysis always operates in the safe, efficient current density band
  • Minimum wear on stack components during partial-load operation

Frequently Asked Questions (FAQ)

An alkaline electrolyser is an electrochemical device that splits water into hydrogen and oxygen gas using DC electricity and a liquid alkaline electrolyte (KOH or NaOH). DC current is applied across a bipolar cell stack — at the cathode, water molecules are reduced to produce hydrogen gas and hydroxide ions; at the anode, hydroxide ions are oxidised to produce oxygen gas. A porous diaphragm separates the two gases while allowing ions to pass, maintaining gas purity and safety.

Brise Chemicals Pvt. Ltd., based in Pune, Maharashtra, is an Indian manufacturer of bipolar alkaline electrolysers for green hydrogen production. They design and fabricate proprietary bipolar stacks with in-house electrode coating technology, offering systems from small pilot scale to multi-MW industrial capacity. They are ISO 9001, ISO 14001, and ISO 45001 certified.

Brise Chemicals' alkaline electrolyser stacks achieve a specific energy consumption of 3.8 to 4.4 kWh per Nm³ of hydrogen — placing them among the most efficient industrial alkaline electrolysers available in India. Lower kWh/Nm³ directly reduces hydrogen production cost per kilogram.

Alkaline electrolysers use a liquid KOH/NaOH electrolyte and conduct hydroxide ions (OH), use non-precious nickel-based catalysts, and have lower CAPEX — making them ideal for large-scale, continuous industrial hydrogen production. PEM electrolysers use a solid polymer membrane, conduct protons (H⁺), use expensive platinum/iridium catalysts, and respond better to rapidly variable power — making them preferred for smaller-scale renewable energy integration where dynamic response is critical.

Brise Chemicals' alkaline electrolysers produce hydrogen at 99.99% (4N) to 99.9999% (6N) purity after passing through the complete gas purification train: gas-liquid separator, scrubber, catalytic De-Oxo unit, and molecular sieve dryer. Oxygen content in the hydrogen stream is maintained below 2 ppm(v) and moisture below 2 ppm(v).

The cost of an alkaline electrolyser in India depends on capacity (kW/MW), operating pressure, purity requirements, and site conditions. At commercial scale, alkaline electrolyser systems range from ₹2.5 crore to ₹8 crore per MW depending on configuration. For a precise quotation customized to your project, contact Brise Chemicals at sales@brisechemicals.com or +91 8956727434.

Yes. Brise Chemicals' alkaline electrolysers are fully compatible with solar PV and wind energy as power sources. The integrated Siemens PLC control system uses an equal distribution control strategy to safely manage variable DC power inputs from renewable sources, routing power to active stacks while placing others in hot-standby during low generation periods.

Brise Chemicals' alkaline electrolysers operate at 1 to 30 barg (gauge pressure). Pressurized operation produces hydrogen at elevated pressure directly from the stack, eliminating the need for a separate low-pressure compressor in many applications, reducing CAPEX and energy consumption.

Current density (measured in A/cm² or mA/cm²) is the electrical current applied per unit of active electrode area in the electrolyser cell. Brise Chemicals' stacks operate at 0.2 to 0.8 A/cm². Higher current density increases hydrogen production rate but also increases cell voltage (and energy consumption). Operating at the optimal current density (typically 0.4–0.6 A/cm²) balances production rate with energy efficiency.

Theoretically, 9 liters (9 kg) of pure water produce 1 kg of hydrogen. In real industrial systems, this rises to 10–11 liters to account for losses in water treatment and purification. For project water planning, Brise Chemicals recommends budgeting 15–18 liters per kg H₂ when including closed-loop cooling circuit makeup water.

Electrolyser Project Execution — End-to-End by Brise Chemicals

Phase What Brise Chemicals Delivers
Pre-FEED / Concept Technology selection, capacity sizing, site assessment, energy balance
FEED Study Front-End Engineering Design, P&ID, plot plan, equipment list, CAPEX estimate
Basic Engineering Package (BEP) Detailed process design, instrumentation philosophy, safety study
Detailed Engineering Construction drawings, equipment datasheets, 3D model
Procurement & Supply Electrolyser stack, BoP equipment, electrical panels, instruments
Construction & Installation Civil, mechanical, piping, electrical, instrumentation installation
Commissioning Pre-commissioning checks, wet commissioning, performance guarantee testing
Training Client operations and maintenance team training
AMC / CMC Long-term maintenance contracts, predictive maintenance, stack O&M

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